Metamorphism is the solid-state
recrystallization of pre-existing
rocks
due to changes in physical and chemical conditions, primarily heat,
pressure, and the introduction of chemically active fluids.
Mineralogical, chemical and
crystallographic changes can occur during this process. Changes at or just beneath Earth's surface due to
weathering and/or
diagenesis are not classified as metamorphism.
[1]
Three types of metamorphism exist:
contact, dynamic and
regional. Metamorphism produced with increasing pressure and temperature conditions is known as
prograde metamorphism. Conversely, decreasing temperatures and pressure characterize
retrograde metamorphism.
Limits of metamorphism
The temperature lower limit of metamorphism is considered to be 100 - 200 °C,
[2] to exclude
diagenetic changes, due to compaction, which result in
sedimentary rocks.
There is no agreement on a pressure lower limit. Some workers argue
that changes in atmospheric pressures are not metamorphic, but some
types of metamorphism can occur at extremely low pressures (see below).
The upper boundary of metamorphic conditions is related to the onset
of melting processes in the rock. The maximum temperature for
metamorphism is typically 700 - 900 °C, depending on the pressure and on
the composition of the rock.
Migmatites
are rocks formed at this upper limit, which contain pods and veins of
material that has started to melt but has not fully segregated from the
refractory residue. Since the 1980s it has been recognized that, rarely,
rocks are dry enough and of a refractory enough composition to record
without melting "ultra-high" metamorphic temperatures of 900 - 1100 °C.
Kinds of metamorphism
Regional metamorphism
Regional or Barrovian metamorphism covers large areas of
continental crust typically associated with mountain ranges, particularly
subduction zones or the roots of previously
eroded mountains. Conditions producing widespread regionally metamorphosed rocks occur during an
orogenic event. The collision of two
continental plates or
island arcs
with continental plates produce the extreme compressional forces
required for the metamorphic changes typical of regional metamorphism.
These orogenic mountains are later eroded, exposing the intensely
deformed rocks typical of their cores. The conditions within the
subducting slab as it plunges toward the
mantle in a subduction zone also produce regional metamorphic effects. The techniques of
structural geology
are used to unravel the collisional history and determine the forces
involved. Regional metamorphism can be described and classified into
metamorphic facies or
metamorphic zones of temperature/pressure conditions throughout the orogenic
terrane.
Contact (thermal) metamorphism
A metamorphic aureole in the Henry Mountains, Utah. The greyish rock on
top is the igneous intrusion, consisting of porphyritic granodiorite
from the
Henry Mountains laccolith,
and the pinkish rock on the bottom is the sedimentary country rock, a
siltstone. In between, the metamorphosed siltstone is visible as both
the dark layer (~5cm thick) and the pale layer below it.
Contact metamorphism occurs typically around
intrusive igneous rocks as a result of the temperature increase caused by the intrusion of
magma into cooler
country rock. The area surrounding the intrusion where the contact metamorphism effects are present is called the
metamorphic aureole.
[3] Contact metamorphic rocks are usually known as
hornfels. Rocks formed by contact metamorphism may not present signs of strong deformation and are often fine-grained.
Contact metamorphism is greater adjacent to the intrusion and
dissipates with distance from the contact. The size of the aureole
depends on the heat of the intrusion, its size, and the temperature
difference with the wall rocks.
Dikes generally have small aureoles with minimal metamorphism whereas large
ultramafic intrusions can have significantly thick and well-developed contact metamorphism.
The metamorphic grade of an aureole is measured by the peak
metamorphic mineral which forms in the aureole. This is usually related
to the metamorphic temperatures of
pelitic
or alumonisilicate rocks and the minerals they form.The metamorphic
grades of aureoles are andalusite hornfels, sillimanite hornfels,
pyroxene hornfels.
Magmatic fluids coming from the intrusive rock may also take part in the
metamorphic reactions.
Extensive addition of magmatic fluids can significantly modify the
chemistry of the affected rocks. In this case the metamorphism grades
into
metasomatism. If the intruded rock is rich in
carbonate the result is a
skarn.
Fluorine-rich magmatic waters which leave a cooling granite may often form
greisens within and adjacent to the contact of the granite. Metasomatic altered aureoles can localize the deposition of metallic
ore minerals and thus are of economic interest.
Hydrothermal metamorphism
Hydrothermal
metamorphism is the result of the interaction of a rock with a
high-temperature fluid of variable composition. The difference in
composition between existing rock and the invading fluid triggers a set
of metamorphic and
metasomatic reactions. The hydrothermal fluid may be magmatic (originate in an intruding magma), circulating
groundwater, or ocean water. Convective circulation of hydrothermal fluids in the ocean floor
basalts
produces extensive hydrothermal metamorphism adjacent to spreading
centers and other submarine volcanic areas. The fluids eventually escape
through vents in the ocean floor known as
black smokers.
[4] The patterns of this hydrothermal alteration is used as a guide in the search for deposits of valuable metal ores.
Shock metamorphism
This kind of metamorphism occurs when either an extraterrestrial object (a
meteorite for instance) collides with the Earth's surface or during an extremely violent
volcanic eruption.
Impact metamorphism is, therefore, characterized by ultrahigh pressure
conditions and low temperature. The resulting minerals (such as SiO
2 polymorphs coesite and
stishovite) and textures are characteristic of these conditions.
Dynamic metamorphism
Dynamic metamorphism is associated with zones of high to moderate strain such as
fault zones.
Cataclasis, crushing and grinding of rocks into angular fragments, occurs in dynamic metamorphic zones, giving cataclastic texture.
The textures of dynamic metamorphic zones are dependent on the depth
at which they were formed, as the temperature and confining pressure
determine the
deformation mechanisms
which predominate. Within depths less than 5 km, dynamic metamorphism
is not often produced because the confining pressure is too low to
produce frictional heat. Instead, a zone of
breccia or
cataclasite is formed, with the rock milled and broken into random fragments. This generally forms a
mélange. At depth, the angular breccias transit into a ductile shear texture and into mylonite zones.
Within the depth range of 5–10 km
pseudotachylite
is formed, as the confining pressure is enough to prevent brecciation
and milling and thus energy is focused into discrete fault planes.
Frictional heating in this case may melt the rock to form
pseudotachylite glass.
Within the depth range of 10–20 km, deformation is governed by
ductile deformation conditions and hence frictional heating is dispersed
throughout
shear zones, resulting in a weaker thermal imprint and distributed deformation. Here, deformation forms
mylonite, with dynamothermal metamorphism observed rarely as the growth of
porphyroblasts in mylonite zones.
Overthrusting
may juxtapose hot lower crustal rocks against cooler mid and upper
crust blocks, resulting in conductive heat transfer and localised
contact metamorphism of the cooler blocks adjacent to the hotter blocks,
and often retrograde metamorphism in the hotter blocks. The metamorphic
assemblages in this case are diagnostic of the depth and temperature
and the throw of the fault and can also be
dated to give an age of the thrusting.
Classification of metamorphic rocks
Metamorphic rocks are classified by their mineral composition, the source rock, also known as a
protolith, and the context (pressure, temperature, hydrological features, etc.) of its formation.
Metamorphic facies
Metamorphic facies are recognizable
terranes
or zones with an assemblage of key minerals that were in equilibrium
under specific range of temperature and pressure during a metamorphic
event. The facies are named after the metamorphic rock formed under
those facies conditions from
basalt. Facies relationships were first described by
Pentti Eskola in 1921.
Metamorphic Facies with regard to temperature and pressure
Facies:
See diagram for more detail.
Metamorphic grades
In the Barrovian sequence (described by
George Barrow
in zones of progressive metamorphism in Scotland), metamorphic grades
are also classified by mineral assemblage based on the appearance of key
minerals in rocks of
pelitic (shaly, aluminous) origin:
Low grade ------------------- Intermediate --------------------- High grade
- Greenschist ------------- Amphibolite ----------------------- Granulite
- Slate --- Phyllite ---------- Schist ---------------------- Gneiss --- Migmatite
- Chlorite zone
-
-
- Biotite zone
-
-
- Garnet zone
-
-
- Staurolite zone
-
-
- Kyanite zone
-
-
- Sillimanite zone
Metamorphic processes
Recrystallization
During recrystallization, the grains making up the
protolith
change shape and size. The identity of the mineral does not change
during this process, only the texture. Recrystallization occurs due to
heating of the protolith. The temperature at which this occurs can vary
depending on the minerals present. Recrystallization generally begins
when temperatures reach above half the melting point of the mineral on
the
Kelvin scale.
[5]
Phase change
Phase change metamorphism is the creating of new minerals with the
same chemical formula as the protolith. This involves a rearrangement of
the atoms in the crystals.
Neocrystallization
Neocrystallization involves the creation of new mineral crystals different from the protolith.
Chemical reactions
digest the minerals of the protolith which yields new minerals. This is
a very slow process as it can also involve the diffusion of atoms
through solid crystals.
Pressure solution
Pressure solution is a metamorphic process that requires a rock to be
under strong pressure from one direction and in the presence of hot
water. During this process mineral of the protolith partially dissolve,
diffuse through the water and precipitate elsewhere.
Plastic deformation
In plastic deformation pressure is applied to the
protolith,
which causes it to shear or bend, but not break. In order for this to
happen temperatures must be high enough that brittle fractures do not
occur, but not so high that diffusion of crystals takes place.
[6]
Prograde and retrograde metamorphism
Metamorphism is further divided into prograde and retrograde
metamorphism. Prograde metamorphism involves the change of mineral
assemblages (
paragenesis)
with increasing temperature and (usually) pressure conditions. These
are solid state dehydration reactions, and involve the loss of volatiles
such as water or carbon dioxide. Prograde metamorphism results in rock
characteristic of the maximum pressure and temperature experienced.
Metamorphic rocks usually do not undergo further change when they are
brought back to the surface.
Retrograde metamorphism involves the reconstitution of a rock via
revolatisation under decreasing temperatures (and usually pressures),
allowing the mineral assemblages formed in prograde metamorphism to
revert to those more stable at less extreme conditions. This is a
relatively uncommon process, because volatiles must be present.